Journal
GREEN CHEMISTRY
Volume 22, Issue 9, Pages 2799-2803Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0gc00677g
Keywords
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Funding
- SERB [EMR/2017/000844]
- JAIN (Deemed-to-be University) start-up research grant
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We report a magnetically separable Cu nanocatalyst (Fe-DOPA-Cu) for the borylation of alkyl halides with alkoxy diboron reagents, providing alkylboronic esters in high yields, with broad functional group tolerance under mild reaction conditions. The procedure is also applicable to the borylation of benzyl chlorides and bromides. Radical clock experiments support a radical-mediated process. Easy recycling of the catalyst resulted in no significant loss of activity up to ten runs.
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