4.8 Article

Three-component aminoselenation of alkenes via visible-light enabled Fe-catalysis

Journal

GREEN CHEMISTRY
Volume 22, Issue 9, Pages 2804-2809

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc04163j

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Funding

  1. National Natural Science Foundation of China [21672047]
  2. SKLUWRE [2018DX02]
  3. Science and Technology Plan of Shenzhen [JCYJ20180306171926120]

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A visible-light-enabled, iron-catalyzed three-component reaction for difunctionalization of alkenes with amines and diselenides has been developed, wherein a photo-excitable Fe-amine complex is proposed as the key intermediate. This ligand- and base-free transformation proceeds smoothly under air atmosphere at room temperature and features broad substrate scope.

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