Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 10, Issue 9, Pages 2931-2947Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cy00087f
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Funding
- Open Project of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University [2019-KF-36]
- Chinese National Natural Science Foundation [21862002, 41663012]
- Ningxia Low-grade Resource High Value utilization and Environmental Chemical Integration Technology innovation team project of North Minzu University
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Two photo-active materials with opposite surface potentials, NiTiO3 with a negative potential and CoAl LDH with a positive potential, have been rationally integrated into two-dimensional (2D) active plane phosphated-CoAl LDH with rich active sites and three-dimensional (3D) hollow NiTiO3 rods with more negative zeta potential. The delicate architecture can efficiently accelerate the separation and migration of photo-excited electrons, make the surface potential more negative, enhance thermodynamic H-2 evolution reaction, and offer rich active planes for photo-catalytic redox reactions. Based on these highlighted photo-catalytic benefits, the optimal composite exhibits more prominent photo-catalytic hydrogen evolution performance compared with NiTiO3 or CoAl LDH materials alone under visible irradiation. In detail, the stereoscopic catalyst, constructed by phosphating CoAl LDH layers anchored on NiTiO3 hollow rods, exhibits a hydrogen evolution activity of about 594 mu mol 5 h(-1), which is 11.6 times and 14.8 times that of CoAl LDH (51 mu mol 5 h(-1)) and NiTiO3 (40 mu mol 5 h(-1)) alone, respectively. Also, the density functional theory results reveal the good conductivity, which is beneficial for charge migration in the hybrid sample. The results from the thoroughly conducted characterization studies such as TEM, SEM, XPS, XRD, UV-vis DRS, transient photocurrent, and FTIR spectroscopy have been well researched and they are in good agreement with each other.
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