4.7 Article

One-dimensional co-crystallized coordination polymers showing reversible mechanochromic luminescence: cation-anion interaction directed rapid self-recovery

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 39, Pages 5267-5270

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09806b

Keywords

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Funding

  1. National Natural Science Foundation of China [21541010, 21771021, 21822501]
  2. Beijing Nova Program [xx2018115]
  3. Fok Ying-Tong Education Foundation [171008]
  4. Beijing Municipal Natural Science Foundation [2152016, 2182028]
  5. Beijing Normal University
  6. Shenyang Normal University [BS201838]

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Three one-dimensional (1D) chain polymers (1D-9HAC, 1D-Cd-9AC, and 1D-Cd-9AC-HBIM) that exhibit different intermolecular interactions and stacking patterns have been designed and synthesized. Only 1D-Cd-9AC-HBIM with rigid (anion) and flexible (cation) units alternately arranged exhibits mechanochromic luminescence, which can be recovered through rapid solvent treatment or a self-recovery process.

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