Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 39, Pages 5247-5250Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09892e
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Funding
- National Science Foundation [CHE-1855531]
- National Science Foundation
- Ruth L. Kirschstein National Research Service Award [F32-GM103211]
- Arnold and Mabel Beckman Foundation
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Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb(v) bis-mu-oxo corrole that photochemically oxidises the C-H bonds of organic substrates. In the case of toluene, the substrate is oxidised to benzaldehyde, a rare example of a four-electron photoreaction.
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