4.5 Article

Submicron Li2MoO4 material prepared by rheological phase method and its evaluation of lithium storage performances

Journal

IONICS
Volume 23, Issue 9, Pages 2269-2273

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s11581-017-2092-z

Keywords

Li2MoO4; Rheological phase method; Sintering; Energy storage and conversion

Funding

  1. Hubei Key Laboratory of Pollutant Analysis & Reuse Technology [PA150105]

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In this paper, submicron Li2MoO4 material was synthesized via rheological phase method. The structure, composition and morphology of the obtained powders were characterized by X-ray diffraction (XRD), X-ray photoelectron spectrometer (XPS) and scanning electron microscope (SEM), respectively. The key calcination temperature was 700 C-o. The particle sizes were about from 100 to 300 nm. As anode material of lithium ion batteries, lithium storage performances of the as-prepared Li2MoO4 were evaluated at different current densities. The best capacity retention was 75.7% of the initial capacity (592.13 mAh g(-1)) after 50 cycles at 0.2 mA cm(-2) in 0.1-2.5 V, and the resistance was about 123.5 Omega, indicating a potential prospect in the application of lithium ions batteries.

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