Journal
CHEMICAL SCIENCE
Volume 11, Issue 19, Pages 4954-4959Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sc00819b
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Funding
- King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research [URF/1/3754]
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A new catalytic method for the direct alkylation of allylic C(sp(3))-H bonds from unactivated alkenes via synergistic organo- and photoredox catalysis is described. The transformation achieves an efficient, redox-neutral synthesis of homoallylamines with broad functional group tolerance, under very mild reaction conditions. Mechanistic investigations indicate that the reaction proceeds through the N-centered radical intermediate which is generated by the allylic radical addition to the imine.
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