Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 18, Issue 19, Pages 3707-3716Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob02735a
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Funding
- National Natural Science Foundation of China [21376222]
- Natural Science Foundation of Zhejiang Province [LY18B060011]
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Mild [2 + 2] photodimerization of enone substrates was induced by donor-acceptor fluorophores. Enone substrates were activated efficiently for anti-head to head dimerizations with a high yield (up to 83%) and high selectivity. The adjustable excited state potential also allows donor-acceptor fluorophores to be used for isomerization of the above substrates, confirming the potential of donor-acceptor fluorophores as energy transfer photocatalysts.
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