4.4 Review

Research Progress of Covalent Organic Framework Materials in Catalysis

Journal

ACTA CHIMICA SINICA
Volume 78, Issue 4, Pages 311-325

Publisher

SCIENCE PRESS
DOI: 10.6023/A19120426

Keywords

covalent organic framework; porous material; COF supporter; catalyst; heterogeneous catalysis

Funding

  1. National Natural Science Foundation of China [51976225]
  2. Dalian National Laboratory for Clean Energy Cooperation Fund, Chinese Academy of Sciences [DNL201916]

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Covalent organic framework materials (COFs) are a class of organic porous materials with large specific surface area, high porosity and crystallinity. Owning to their special nature of functional versatility and easy modification, COFs can be designed to be efficient catalysts either embed functional active sites into the skeleton through a top-down strategy, or load metal nanoparticles into the framework via a post-modification approach. These studies have laid the foundation for the extension of COF's application in heterogeneous and other catalytic fields. The synthetic strategy and application of COF in different types of catalytic reactions are reviewed in this paper. Moreover, the current research situation of COF catalyst is summarized and prospected. Finally, the remaining challenges in this field are also indicated.

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