Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 11, Pages 1395-1417Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00377h
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Funding
- Ministry of Science and Technology of the People's Republic of China [2016YFA0602900]
- National Natural Science Foundation of China [21971072, 21672072]
- Fundamental Research Funds for the Central Universities [2018ZD16]
- Pearl River S&T Nova Program of Guangzhou [201906010072]
- Guangdong Provincial Training Program of Innovation and Entrepreneurship for Undergraduates [S201910561219]
- Open Fund of Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates [2019B030301003]
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Transition metal-catalyzed C-S bond formation reactions have attracted considerable attention in the recent years. In this regard, palladium-catalyzed C-S bond formation is typically attractive because it can effectively assemble structurally diverse unsymmetrical aryl sulfides and functionalized sulfones under mild conditions with high regioselectivities. In this review, palladium-catalyzed C-S bond formation reactions are summarized and discussed in detail with the focus on sulfenylation and sulfonylation reactions involving aryl/heteroaryl C-H bonds, alkynes, aryl halides, electron-rich benzoic acid derivatives, arylhydrazines, and organosilicon reagents. Some representative synthetic strategies and their transformation application along with reaction mechanisms are also highlighted.
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