Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 8, Issue 21, Pages 10747-10754Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ta04244g
Keywords
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Funding
- Department of Chemistry startup funds
- Institute for Critical Technology and Applied Science
- National Natural Science Foundation of China [51871160, 51671141, 51471115]
- U.S. DOE Office of Science Facility [DE-SC0012704]
- DOE Office of Science [DE-AC02-06CH11357]
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-76SF00515]
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Enhancing the oxygen evolution reaction (OER) performance of NiO materials will greatly expand their applications as low-cost, bifunctional electrocatalysts for water splitting reactions. Introducing stress into the surface layer of catalysts represents an effective method to enhance their catalytic reactivity. Herein, we create compressive stress at the NiOOH/NiO interface using the battery conversion chemistry and in situ Ni to NiOOH transformation. As a result, the OER performance is enhanced by 20 fold compared with that of pure NiO. However, due to the corrosive environment that the electrocatalyst experiences under OER conditions, the stress is released after several CV cycles. The present study demonstrates the importance of interfacial stress that can be produced from in situ surface phase transformation of the electrocatalyst, as well as highlights the challenge of maintaining the mechanical stress under OER conditions during long-term applications.
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