4.7 Article

A new approach to the synthesis of trinuclear gold(I) imidazolate complexes and their silver(I)-induced photoluminescence behavior

Journal

DALTON TRANSACTIONS
Volume 49, Issue 20, Pages 6561-6565

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt01246g

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Funding

  1. Spanish Ministerio de Economia y Competitividad [MINECO-FEDER CTQ2015-66959-P, MAT2015-66747-R/RTI2018-099756-B-I00]
  2. Universidad de Oviedo [PAPI-19-GR-2011-0027, PAPI-19-PUENTE-5]
  3. Principado de Asturias
  4. MINECO

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New trinuclear gold(I) N-arylimidazolate cluster complexes have been synthesized from cationic [Au(CNR)(2)](+) isocyanide complexes and their structure and photoluminescence behavior have been compared with those of their 1-methylimidazolate counterpart. A drastic change in their photophysical properties was observed upon coordination of the Ag+ cation.

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