Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 42, Pages 5637-5640Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc01447h
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Funding
- SERB, India [SB/S1/IC-56/2012, EMR/2017/003109]
- DST-CERI, India [DST/TM/CERI/C228]
- CSIR, India
- DST, India
- DAE-BRNS, India
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Calix[3]pyrroles were synthesized for the first time. These macrocycles display versatile guest binding ability based on the bridges connecting the two alpha-positions of the tripyrrane moiety e.g. with an ethene bridge they showed colorimetric sensing of fluoride and cyanide ions, whereas with a phenylene spacer they exhibited fluorometric sensing of fluoride ions only, and the macrocycle with an ethylene unit acted as a host towards the water molecule with unique penta-coordinated oxygen in the solid state.
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