Journal
CURRENT ORGANIC SYNTHESIS
Volume 12, Issue 6, Pages 795-805Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157017941206150828112854
Keywords
[3,3] sigmatropic; organocatalysis; chiral Lewis acids; claisen rearrangement; asymmetric rearrangement; catalysis
Categories
Funding
- CAPES
- CNPq
- FINEP-MCT
- DPP-UnB
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The Claisen rearrangement, an important C-C bond forming reaction, has been used enormously for many decades in the synthesis of important class of compounds. This review covers developments in this rearrangement since 2008, discusses important aspects about the asymmetric Claisen rearrangement catalyzed by chiral organometallic Lewis acids or organic Bronsted-Lowry acids.
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