Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 44, Pages 5993-5996Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09827e
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Funding
- National Natural Science Foundation of China [21676078]
- Scientific Research Fund of Hunan Provincial Education Department [19A323]
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Incorporation of azobenzene into the linker of bimetallic chiral salen Ti-IV catalysts allowed the photoswitchable arrangement of the two Ti(salen) units through cis/trans photoisomerization of azobenzene. The differently arranged Ti(salen) units changed their cooperative function to reflect the positional relationships, as a result, their efficiency as cooperative catalysts in asymmetric sulfoxidation could be readily controlled by light stimuli.
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