Journal
NEW JOURNAL OF CHEMISTRY
Volume 44, Issue 21, Pages 8728-8735Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nj01349h
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21601163]
- Program for the Top Young Academic Leaders of North University of China
- Natural Science Foundation of Shandong Province [ZR2016BQ35]
Ask authors/readers for more resources
A 2D zinc(ii)-based metal-organic framework (Zn-MOF) formulated as [Zn(bimpy)(1,4-ndc)]center dot H2O (1, bimpy = 3,5-bis(1-imidazolyl)pyridine and 1,4-ndc = 1,4-naphthalenedicarboxylic acid) was synthesized by solvothermal reaction. Complex 1 exhibits high water and pH-independent stability. It can detect Fe3+ and ascorbic acid (AA) as a turn-off fluorescence probe and a turn-on fluorescence probe in aqueous solution with high sensitivity and selectivity, respectively. The detection limits of 1 for Fe3+ and AA are about 8.82 x 10(-7) M and 6.12 x 10(-7) M, respectively. The fluorescence intensity of the Fe3+@1 system can be obviously recovered after adding AA due to the reduction of Fe3+, which exhibits a fluorescence turn-on signal (turn-off-on) for Fe3+@1 toward AA with a low detection limit (3.53 x 10(-7) M). Complex 1 still exhibits good detection of Fe3+ and AA after washing and using for five cycles. Additionally, two different multi-input molecular logic gates are established. One is used to distinguish the effect of Fe3+ and Fe2+ on the fluorescence of complex 1, and the other is to further explain the regulation of Fe3+ and AA on the fluorescence of complex 1. This work shows that complex 1 is the first MOF-based turn-on fluorescent probe for both Fe3+ and AA in aqueous solution.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available