Journal
DALTON TRANSACTIONS
Volume 49, Issue 21, Pages 6969-6973Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt01146k
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Funding
- NSFC [21971203, 21871219, 21773130]
- Shenzhen Science and Technology Program [JCYJ20180306170859634]
- Xi'an Municipal Bureau of Science and Technology [201805056ZD7CG40]
- State Key Laboratory for Mechanical Behavior of Materials [20182006]
- Cyrus Chung Ying Tang Foundation
- Fundamental Research Funds for the Central Universities
- Guangdong Natural Science Funds for Distinguished Young Scholar [2018B030306009]
- China Postdoctoral Science Foundation [2019T120891, 2018M643615]
- Young Elite Scientists Sponsorship Program by CAST [2017QNRC001]
- Shaanxi National Science Foundation [2019JQ-016]
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An air-stable dysprosium(III) complex, [C(NH2)(3)](4)[DyF(piv)(4)]( piv)(2) ( piv = pivalate), with a terminal fluoride ligand protected by forming extensive hydrogen bonds with peripheral guanidiniums has been isolated. Though the magnetic data failed to determine the energy barrier for the magnetic reversal (U-eff) accurately, the fine emission spectrum of the F-4(9/2) -> H-6(15/2) transition at 4.2 K and ab initio calculations reveal that the U-eff is about 376(20) K, which is among the highest for high-coordinate (coordination numbers >= 9) lanthanide mononuclear magnets.
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