4.7 Article

Pressure-induced dehydrogenative coupling of methane to ethane by platinum-loaded gallium oxide photocatalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 47, Pages 6348-6351

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc01730b

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Funding

  1. Japan Science and Technology Agency (JST), Precursory Research for Embryonic Science and Technology (PRESTO) [JPMJPR15S1, JPMJPR16S2, JPMJPR18T1]

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Pt/Ga(2)O(3)exhibited high activity for dehydrogenative coupling of methane into ethane (2CH(4)-> C2H6+ H-2) in a fixed-bed flow reactor at 25 degrees C under 254 nm UV irradiation. The C(2)H(6)formation was negligible at CH(4)pressure of 10 kPa, but it was linearly increased with an increase in the pressure to 300 kPa.

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