Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 46, Pages 6213-6216Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc02645j
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Funding
- National Natural Science Foundation of China [21671066]
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A novel Pd/Au vinylene complex synthesized through cyclization of sigma,pi-heterodinuclear (Pd/Au) acetylide reacted with iodobenzene to give a Pd vinyl species, where the presence of a strong metallophilic PdMIDLINE HORIZONTAL ELLIPSISAu interaction was found to facilitate phenyl transmetalation from Pd to Au, followed by reductive elimination at Au.
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