Journal
POLYMER CHEMISTRY
Volume 11, Issue 22, Pages 3709-3715Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0py00369g
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Funding
- Natural Science Foundation of China [21602028]
- Beijing National Laboratory for Molecular Sciences [BNLMS201913]
- Fuzhou University
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The excited state acidity of ESPT molecules is first demonstrated as a suitable means of catalysis for the light-regulated ring-opening polymerization of lactones, in combination with a photosensitizer as the energy-transfer cocatalyst to harness light. Under blue light irradiation, this method could afford metal-free polyesters with well-controlled molecular weights and narrow dispersities.
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