4.6 Article

Directionality of PMIDLINE HORIZONTAL ELLIPSISO pnicogen bonding in light of geometry corrected statistical analysis

Journal

NEW JOURNAL OF CHEMISTRY
Volume 44, Issue 23, Pages 9607-9610

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nj01683g

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Funding

  1. Council of Scientific and Industrial Research, India [01(2908)/17/EM-II]
  2. CSIR
  3. Pondicherry University

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Statistical analysis, after cone correction, on X3PMIDLINE HORIZONTAL ELLIPSISO and X4PMIDLINE HORIZONTAL ELLIPSISO pnicogen bonds suggests that the angle X-PMIDLINE HORIZONTAL ELLIPSISO prefers linearity and the linearity is more prominent in the case of X3PMIDLINE HORIZONTAL ELLIPSISO. With an increase in the electronegativity of X, the preference for linearity also increases.

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