Journal
DALTON TRANSACTIONS
Volume 49, Issue 23, Pages 7938-7944Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt01599g
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Funding
- Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences Heavy Element Chemistry Program of the U.S. Department of Energy (DOE) at LBNL [DE-AC02-05CH11231]
- National Science Foundation Graduate Research Fellowship Program [DGE 1106400]
- UC Berkeley
- German Academic Exchange Service (DAAD)
- University of Innsbruck
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We describe the functionalisation of the previously reported uranium(iii) beta-diketiminate complex (BDI)UI2(THF)(2)(1) with one and two equivalents of a sterically demanding 2,6-diisopropylphenolate ligand (ODipp) leading to the formation of two heteroleptic complexes: [(BDI)UI(ODipp)](2)(2) and (BDI)U(ODipp)(2)(3). The latter is a rare example of a tetrahedral uranium(iii) complex, and it shows single-molecule magnet behaviour.
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