Journal
DALTON TRANSACTIONS
Volume 49, Issue 22, Pages 7324-7327Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt01090a
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Funding
- National Natural Science Foundation of China [21871204]
- 1000-Youth Talents Plan
- PAPD
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Neutral molecular zinc(ii) dihydrides supported by N-heterocyclic carbene ligands bearing a pendant phosphine group were synthesized and then reacted with carbon dioxide to afford zinc diformates. The zinc dihydrides were found to be active catalysts for hydroboration of carbon dioxide under mild conditions, selectively giving boryl formate, bis(boryl)acetal, or methoxy borane compounds by changing the nature of the borane reductant.
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