4.6 Article

The Baeyer-Villiger rearrangement with metal triflates: new developments toward mechanism

Journal

RSC ADVANCES
Volume 10, Issue 36, Pages 21382-21386

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra03335a

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Based on MS analysis, the mechanism of the Baeyer-Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf)(3)and Er(OTf)(3)) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected.

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