Journal
CHEMICAL SCIENCE
Volume 11, Issue 23, Pages 6053-6057Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sc02417a
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Funding
- Friedrich Ebert Foundation
- Carl Zeiss Foundation for the research network ELYSION
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Electrochemical decarboxylation of aryloxyacetic acids followed by fluorination provides easy access to fluoromethyl aryl ethers. This electrochemical fluorodecarboxylation offers a sustainable approach with electric current as traceless oxidant. Using Et3N center dot 5HF as fluoride source and as supporting electrolyte, this simple electrosynthesis affords various fluoromethoxyarenes in yields up to 85%.
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