Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 48, Pages 6583-6586Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc02525a
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Funding
- National Natural Science Foundation of China [21971118, 21722106]
- USA National Science Foundation [CHE-1664379]
- Fondecyt [1180683]
- [PGC2018-098212-B-C21]
- [EUR2019-103825]
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In this work, we report a dimeric cluster anion, {[CuGe(9)Mes](2)}(4-), which was isolated as the [K(2,2,2-crypt)](+)salt and characterized by using single-crystal X-ray diffraction and ESI mass spectroscopy. The title cluster represents the first locally sigma-antiaromatic compound in the solid state, as well as the first heteroatomic antiaromatic compound.
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