Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 53, Pages 7233-7236Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc02472d
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Funding
- National Key R&D Program of China [2018YFA0704502, 2017YFA0206800]
- Strategic Priority Research Program of CAS [XDB20000000]
- Key Research Program of Frontier Science, CAS [QYZDY-SSW-SLH025]
- NSFC [21671189, 21731006, 21901242]
- Youth Science Research Program of Fujian Jiangxia University [JXZ2018003]
- Youth Innovation Promotion Association CAS
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Three unprecedented multi-cluster copper(I) halides (MCCHs) have been assembled using conformationally flexible ligands. Further explorations demonstrate that the conformational compliance of the ligands may be the key to trap and stabilize the various copper(I)-halide clusters in one system, which opens a new way for the construction of multi-Cu(I)-cluster complexes. Moreover, the MCCHs show distinctive temperature-dependent photoluminescence.
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