4.7 Article

Salt nanoconfinement in zirconium-based metal-organic frameworks leads to pore-size and loading-dependent ionic conductivity enhancement

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 53, Pages 7245-7248

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03147j

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Funding

  1. Joint Center for Energy Storage Research (JCESR), an Energy Innovation Hub - U.S. Department of Energy, Office of Science, Basic Energy Sciences

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The effect of nanoscale confinement of a salt on its ionic conductivity was studied for [NEt4][TFSI] melt-loaded in three isoreticular zirconium-based MOFs: UiO-66, UiO-67, and PCN-56. Conductivity of the MOF-salt composites was up to a factor of 50 higher than the pure salt, and maximized with slightly less than full loading of the MOFs.

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