Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 52, Pages 7100-7103Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc02851g
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Funding
- research grant SERB-India [CRG/2018/003915]
- J. C. Bose Fellowship (SERB)
- UGC-India
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meta-Selective C-H nitration of phenol derivatives was developed using a Ru-catalyzed sigma-activation strategy. Cu(NO3)(2)center dot 3H(2)O was employed as the nitrating source, whereas Ru-3(CO)(12)was found to be the most suitable metal catalyst for the protocol. Mechanistic studies suggested involvement of anortho-C-Ar-H metal intermediate, which promotedmeta-electrophilic aromatic substitution and silver-assisted free-radical pathway.
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