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Recent developments in the construction and applications of platinum-based metallacycles and metallacages via coordination

Journal

CHEMICAL SOCIETY REVIEWS
Volume 49, Issue 12, Pages 3889-3919

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cs00038h

Keywords

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Funding

  1. National Natural Science Foundation of China [21503185, 21404062]
  2. Natural Science Foundation of Zhejiang Province [LY20B040003]
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions
  4. NIH [R01-CA215157]

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Coordination-driven suprastructures have attracted much interest due to their unique properties. Among these structures, platinum-based architectures have been broadly studied due to their facile preparation. The resultant two- or three-dimensional (2D or 3D) systems have many advantages over their precursors, such as improved emission tuning, sensitivity as sensors, and capture and release of guests, and they have been applied in biomedical diagnosis as well as in catalysis. Herein, we review the recent results related to platinum-based coordination-driven self-assembly (CDSA), and the text is organized to emphasizes both the synthesis of new metallacycles and metallacages and their various applications.

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