Journal
RSC ADVANCES
Volume 10, Issue 42, Pages 24862-24866Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra05295g
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Funding
- JSPS KAKENHI [JP17H04875, JP16H06514, JP18H04265, JP19K22204]
- Nissan Chemical Corporation
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A proof-of-concept for the one-step, synthetically challenging cyclic and acyclic perfluoroalkylation of (hetero)arenes driven by the valence change of a vitamin B(12)derivative as a cobalt catalyst in the presence of fluoroalkylating reagents (X(CF2)(4)X) is presented. The consecutive formation of cobalt-carbon bonds and generation of fluoroalkyl radicals by homolysis are the key steps for the reaction to proceed.
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