Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 54, Pages 7483-7486Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09902f
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Funding
- National Natural Science Foundation of China [21402062]
- Science and Technology Project of Lianyungang High-tech Industrial Development Zone [ZD201920]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- First-class Undergraduate Majors Construction Program of Jiangsu Province
- Key Discipline Construction Program of Jiangsu Province
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX19_2265]
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A copper-catalyzed borylative amidation of vinyl arenes with isocyanates and bis(pinacolato)diboron has been developed. This new protocol, which can be performed on a gram-scale, utilizes isocyanates as simple precursors to provide access to a range of boryl alkyl amides. The products contain valuable amide and boronate, which are amenable for further elaboration, and have versatile synthetic utilities.
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