Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 35, Pages 4761-4764Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc01872d
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Funding
- Fonds der chemischen Industrie (Kekule fellowship)
- Heinrich Heine University [F-2018/1460-4]
- Deutsche Forschungsgemeinschaft [387284271 SFB 1349]
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We present the synthesis of a porous, organic [4+4] imine cage containing perfluorinated aromatic panels. Gas adsorption experiments show an uptake of 19.0 wt% CO2 (4.2 mmol g(-1), 273 K and at 1 bar) and 1.5 wt% H-2 (7.5 mmol g(-1), 77 K and at 1 bar) for the specific surface area of 536 m(2) g(-1) of the crystalline material obtained directly from the reaction mixture, combined with an outstanding thermal stability, making it a very interesting porous material suitable for gas adsorption.
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