4.6 Article

Polymer field-effect transistor memory based on a ferroelectric nylon gate insulator

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 8, Issue 16, Pages 5535-5540

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9tc06868f

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Funding

  1. Alexander von Humboldt Foundation
  2. National University of Science and Technology (Pakistan)
  3. Max Planck Society

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Nylons are one of the most successful commercialized polymers and can also be made to have ferroelectric properties. However, use of nylons in microelectronic devices like ferroelectric field-effect transistors has proven to be challenging due to the difficulty in achieving ferroelectric thin films by solution processing. In this work, we present ferroelectric field-effect transistor (FeFET) memory with a ferroelectric nylon-11 gate. Water quenching allows for the fabrication of ultra-smooth ferroelectric nylon-11 thin films. A bottom-gate top-contact (BGTC) FeFET is successfully demonstrated with a p-type semiconducting polymer, poly(triaryl amine) (PTAA), as a channel. The nylon-11 FeFET shows reliable memory functionality. The demonstration of nylon-11 based FeFETs makes nylons a promising material for applications in organic electronics, such as flexible devices, electronic textiles and biomedical devices.

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