4.8 Article

Manganese MOF Enables Efficient Oxygen Evolution in Acid

Journal

ACS MATERIALS LETTERS
Volume 2, Issue 7, Pages 798-800

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsmaterialslett.0c00123

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Funding

  1. Natural Sciences and Engineering Research Council (NSERC) of Canada
  2. University of Toronto Scarborough start-up fund
  3. University of Toronto Scarborough research competitiveness fund

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The oxygen evolution capabilities of a manganese metal-organic framework (MOF) are demonstrated in acid (pH 1.3) for the first time. The MOF/carbon black composite significantly outperforms MnO2, a known non-noble acidic OER catalyst, exhibiting overpotentials of 539 and 764 mV (vs 715 and 898 mV for MnO2) for a current density of 10 and 50 mA/cm(2), respectively.

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