4.7 Article

Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 56, Pages 7738-7740

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc02349c

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Funding

  1. Australian Research Council [DP170102695, DP190100723]

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The reaction of [Rh-2(mu-C)Cl-2(PPh3)(4)] with 1,1 '-bis(diphenylphosphino)ferrocene (dppf) affords the mu-carbido complex [Rh-2(mu-C)Cl-2(mu-dppf)(2)] which reacts with PhICl(2)to provide a diamagnetic dirhodium(ii) carbido complex [Rh-2(mu-C)Cl-4(mu-dppf)(2)].

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