Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 57, Pages 7941-7944Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc02662j
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Funding
- NSFC [21572090, 21871123]
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We present herein a method for the controllable synthesis of 3-aryl-benzomorpholine and 2-aryl-benzomorpholine cycloadductsviacross-coupling/annulation between electron-rich 2-aminophenols and 4-vinylphenols. Molecular oxygen was successfully used in the reaction as the terminal oxidant and the complete inversion of chemoselectivity was achieved by the adjustment of the solvents and bases at room temperature.
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