Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 57, Pages 7977-7980Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03309j
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Palladium/copper-cocatalyzed decarbonylative alkynylation of acyl fluorides with alkynylsilanes is described. This reaction not only effectively inhibits the formation of undesired homocoupled products by avoiding the addition of a base, but also exhibits a wide substrate scope to provide a general access to diverse unsymmetrical diarylethynes.
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