Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 42, Issue 47, Pages 28247-28253Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2017.09.135
Keywords
Hydrogen production; Fluidised bed; Iron-chromium catalyst
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This investigation studies possibility of the generation of hydrogen through the partial oxidation of methanol, using N2O as the oxidant, over a commercial iron-chromium catalyst in the form of a fluidised bed. A 95% yield of hydrogen was achieved at 350 degrees C. The most important advantages of the proposed solutions are: possibility of utilization of renewable bio-methanol and waste N2O; easy control over the temperature of the process and thus, control over the product distribution through the introduction of a catalyst in a fluidised state, use of an industrial catalyst which is cheap, available, stable, has a long lifetime; high compression strength and abrasion resistance. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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