Journal
ORGANIC COMMUNICATIONS
Volume 13, Issue 2, Pages 65-78Publisher
ACG PUBLICATIONS
DOI: 10.25135/acg.oc.80.20.05.1639
Keywords
Phthalocyanines; photochemical studies; singlet oxygen; quantum yields; metal chelating; DPPH radical scavenging
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Funding
- Scientific and Technological Research Council of Turkey (TUBITAK) [TBAG-113Z699, KBAG-115Z446, 217Z043]
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In this study, two new phthalocyanines (M = Zn and Co) were synthesized using the (E)-4-(4-(3-(4-(benzyloxy)phenyl)acryloyl)phenoxy)phthalonitrile (3) as ligand prepared from the chemical reaction of 4-nitrophthalonitrile with (E)-3-(4-(benzyloxy)phenyl)-1-(4-hydroxyphenyl)prop-2-en-l-one (2). All compounds were characterized using by H-1-NMR, C-13-NMR, UV-Vis, FT-IR, and MALDI-TOF mass spectra. Singlet oxygen quantum yields of the synthesized compounds, aggregates in different solutions, metal chelating and 2,2-Diphenyl-1-picrylhydrazyl (DPPH) radical scavenging properties were reported.
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