Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 15, Pages 2029-2034Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00415d
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Funding
- National Natural Science Foundation of China [21602083]
- Natural Science Foundation of Jiangsu Province [BK20160160]
- Soochow University [Q410900520]
- [JUSRP51703A]
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A set of copper-catalyzed sulfonylcyanations of vinylarenes with readily accessible arylsulfonyl chlorides and trimethyl cyanide was accomplished under mild conditions, thus providing a step-economic streamlined route to various decorated beta-sulfonyl nitriles with good regioselectivity and functional group tolerance. Preliminary mechanistic studies suggested that this type of reaction undergoes a classic radical chain process.
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