Journal
NEW JOURNAL OF CHEMISTRY
Volume 44, Issue 29, Pages 12435-12439Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nj01931c
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Funding
- Van Yuzuncu Yil University Scientific Research Project Coordination Unit [2015-FBE-YL354]
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Palladium nanoparticles stabilized by an MIL-101 metal-organic framework (Pd@MIL-101) are synthesized by a novel synthesis approach. A Pd@MIL-101 catalyst facilitates H(2)generation from the methanolysis of ammonia-borane with record catalytic activity (TOF = 1080 min(-1)) at room temperature. Moreover, the exceptional stability of Pd@MIL-101 makes it a reusable heterogeneous catalyst in this catalytic transformation.
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