4.7 Article

Transition metal decorated soft nanomaterials through modular self-assembly of an asymmetric hybrid polyoxometalate

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 59, Pages 8237-8240

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03554h

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Funding

  1. Low Dimensional Materials and Interfaces Doctoral Training Programme at the University of Nottingham
  2. Leverhulme Trust [RPG2016-442]
  3. Engineering and Physical Sciences Research Council (EPSRC) [EP/L022494/1]
  4. EPSRC [1938024, EP/S031170/1] Funding Source: UKRI

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An asymmetrically functionalised Wells-Dawson organic-inorganic hybrid polyoxometalate has been post-functionalised by Pt(2+)coordination, and demonstrates self-assembly into surface-decorated micellar nanostructures. This multifunctional hybrid material is found to be a redox-active soft nanomaterial and demonstrates a new molecular design strategy with potential for applications in photo- or electro-catalysis.

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