Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 62, Pages 8747-8749Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03302b
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Funding
- National Science Foundation [CHE-1654691]
- Auburn University
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The total synthesis of the lignan-based cyclobutane di-O-methylendiandrin A has been achieved using diastereoselective, vicinal alkylation and transannular McMurry reactions of a macrocyclic 1,4-diketone as key transformations for establishing relative stereochemistry and furnishing the strained 4-membered ring of the natural product.
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