Journal
ACS APPLIED NANO MATERIALS
Volume 3, Issue 7, Pages 6598-6608Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsanm.0c01049
Keywords
TiO2; photoelectrochemical water oxidation; NiFe layered double hydroxide; doping
Funding
- National Natural Science Foundation of China [51702025, 51874050]
- Top-notch Academic Programs Project of Jiangsu Higher Education Institutions
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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We demonstrate the fabrication of controlled Co-doped TiO2 nanowire arrays modified by an ultrathin NiFe layered double hydroxide (LDH) as a photoanode for enhanced photoelectrochemical water-splitting application. The Co-TiO2/NiFe LDH heterostructured photoanode exhibited a significantly enhanced photocurrent density of 1.66 mA/cm(2) at 1.23 V versus reversible hydrogen electrode, up to 1.86 times higher than that of bare TiO2, mainly because of the improved charge separation, suppressed charge recombination, and increased kinetics of the surface water oxidation reaction. The X-ray photoelectron spectroscopy measurements confirmed that TiO2 photoanodes possessed abundant oxygen vacancies, which could effectively boost the hole trapping/transfer and supply more active sites for water oxidation. Photoinduced electrochemical impedance spectroscopy indicated that enhanced conductivity could also promote photogenerated electron transfer from the thin film to the substrate. The Co-TiO2/NiFe LDH photoelectrode presented excellent photostability under 7 h of continuous illumination and an increased photoconversion of 0.55%, 2.64 times higher than that of a bare TiO2 photoelectrode.
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