Journal
CHEMICAL SOCIETY REVIEWS
Volume 49, Issue 15, Pages 5310-5358Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cs00340a
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Funding
- National Natural Science Foundation of China [NSFC 21871127, 91856203]
- Shenzhen Science and Technology Innovation Commission [JCYJ20170412140251576, JCYJ20170817111150174]
- Southern University of Science and Technology
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Direct C-H bond functionalization catalyzed by non-precious transition metals is an attractive strategy in synthetic chemistry. Compared with the precious metals rhodium, palladium, ruthenium, and iridium commonly used in this field, catalysis based on non-precious metals, especially the earth-abundant ones, is appealing due to the increasing demand for environmentally benign and sustainable chemical processes. Herein, developments in iron- and cobalt-catalyzed C(sp(3))-H bond functionalization reactions are described, with an emphasis on their applications in organic synthesis,i.e., the synthesis of natural products and pharmaceuticals and/or their modification.
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