Journal
GREEN CHEMISTRY
Volume 22, Issue 15, Pages 4878-4883Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc03936h
Keywords
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Funding
- NSFC [21971098, 21432003]
- CIFMS [2019-I2M-5-074]
- Fundamental Research Funds for the Central Universities [lzujbky-2018-k9]
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The visible-light induced regioselective fluoroalkylfluoroalkylselenolation of unactivated alkenes was realized under metal and oxidant free conditions. The reaction was enabled by incorporation of two distinct photoinduced processes for the generation of two radical coupling partners. -CF3, -R-f, -CF2CO2Et, -CCl3, -SeCF3, and -SeR(f)were all successfully introduced to alkenes in good to excellent yields. The mild conditions showed a general substrate tolerance, and offered an efficient strategy for the late-stage functionalization of complex natural products and drug molecules.
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