Journal
MATERIALS CHEMISTRY FRONTIERS
Volume 4, Issue 8, Pages 2428-2434Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qm00151a
Keywords
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Funding
- Shenzhen Technology and Innovation Commission [JCYJ20170413173814007]
- Hong Kong Research Grants Council [T23-407/13N, N_HKUST623/13, 16305915, 16322416, 606012, 16303917]
- Hong Kong Innovation and Technology Commission [ITC-CNERC14SC01, ITS/083/15]
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Non-fullerene acceptors (NFAs) have attracted significant research attention as they enable high-performance organic solar cells (OSCs). Recently, a new NFA named Y6 was reported to yield highly efficient OSCs with efficiency up to 15.7%. Then, the research interests regarding the structure-property relationship and further structural optimization of Y6 have risen sharply. In this study, we report a new NFA,N3-4Cl, usingIC-2Clas the end group and replacing the alkyl side chains on theN-position of the pyrrole unit with branched side chains on the third position. The combined substitution on Y6 yields electronic effects on energy levels and thus the open-circuit voltage (V-oc) of the corresponding OSCs. The lowest unoccupied molecular orbital (LUMO) level ofN3-4Clis up-shifted compared to that ofY6-4Cl; thus, a higherV(oc)of 0.85 V is obtained. In addition,PM6: anN3-4Clblend film can also maintain an optimal blend morphology with reasonably high and balanced charge mobility, which leads to a high fill factor (FF) of up to 74.9%. As a result,PM6:N3-4Cl-based device reached a PCE of 16.5% in binary devices. The results suggest that tuning the side chains of NFAs is an effective method for optimizing energy levels and aggregation properties, thus enhancing the OSC performances.
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