Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 67, Pages 9600-9603Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00741b
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Funding
- Helen Co., Ltd
- KIST Institutional Program [2E30460]
- Department of Chemistry at Oregon State University
- KISTI Supercomputing Centre [KSC-2019-CRE-0149]
- National Research Foundation of Korea [2E30250] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Herein, we present a new strategy to design metal-organic frameworks (MOFs) as adsorbents for ammonia (NH3) vapour. The linking ligand is functionalized with a sterically hindered Lewis acidic boron (B) centre, allowing efficient capture of NH3 and easy recycling of the MOF by simply heating at low temperature. The recycled MOF material can be used for NH3 capture for at least 5 cycles without losing its crystallinity or its luminescence properties.
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