4.7 Article

DirectN-formylation of nitroarenes with CO2

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 67, Pages 9620-9623

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03098h

Keywords

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Funding

  1. National Key Research and Development Program of China [2019YFA0905100]
  2. National Natural Science Foundation of China [21772142, 21971186, 21961142015]
  3. Tianjin University

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Herein we describe a straightforwardN-formylation of nitroarenes with CO(2)to accessN-aryl formamides exclusively in the presence of iron and hydrosilane as additives. This protocol showcases a good tolerance of a wide range of nitroarenes and nitroheteroarenes.

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